What is vapour pressure? Explain the statement: "In an open vessel,the rate of vaporization is constant,yet equilibrium is not established."

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Vapour pressure is the pressure exerted by the vapour of a liquid in equilibrium with the liquid at a given temperature in a closed vessel.
Equilibrium is only possible in a closed vessel where the rate of vaporization equals the rate of condensation.
In an open vessel,the vapour molecules escape into the surrounding atmosphere. Consequently,the rate of vaporization $(Liquid \rightarrow Gas)$ is greater than the rate of condensation $(Gas \rightarrow Liquid)$.
Since the vapour is continuously lost to the surroundings,the reverse process cannot occur at the same rate as the forward process,and thus,equilibrium is never established.
Even though the rate of vaporization remains constant at a fixed temperature,the system cannot reach equilibrium because the condensation process is effectively absent or negligible.

Explore More

Similar Questions

For a reversible reaction,if the concentration of reactants is increased,the equilibrium constant of the reaction

In which of the following reactions,the concentration of product is higher than the concentration of reactant at equilibrium? $(K = \text{equilibrium constant})$

Which of the following conditions represents an equilibrium?

Which of the following is not a characteristic property of chemical equilibrium?

Mark the correct statement in a reversible reaction.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo